全文获取类型
收费全文 | 12760篇 |
免费 | 1923篇 |
国内免费 | 840篇 |
专业分类
化学 | 4045篇 |
晶体学 | 319篇 |
力学 | 1780篇 |
综合类 | 230篇 |
数学 | 4912篇 |
物理学 | 4237篇 |
出版年
2023年 | 159篇 |
2022年 | 201篇 |
2021年 | 315篇 |
2020年 | 304篇 |
2019年 | 276篇 |
2018年 | 300篇 |
2017年 | 525篇 |
2016年 | 616篇 |
2015年 | 561篇 |
2014年 | 668篇 |
2013年 | 1074篇 |
2012年 | 698篇 |
2011年 | 727篇 |
2010年 | 686篇 |
2009年 | 764篇 |
2008年 | 818篇 |
2007年 | 878篇 |
2006年 | 702篇 |
2005年 | 560篇 |
2004年 | 597篇 |
2003年 | 586篇 |
2002年 | 476篇 |
2001年 | 335篇 |
2000年 | 318篇 |
1999年 | 296篇 |
1998年 | 262篇 |
1997年 | 191篇 |
1996年 | 215篇 |
1995年 | 196篇 |
1994年 | 160篇 |
1993年 | 135篇 |
1992年 | 108篇 |
1991年 | 86篇 |
1990年 | 73篇 |
1989年 | 59篇 |
1988年 | 64篇 |
1987年 | 52篇 |
1986年 | 44篇 |
1985年 | 67篇 |
1984年 | 39篇 |
1983年 | 27篇 |
1982年 | 37篇 |
1981年 | 29篇 |
1980年 | 46篇 |
1979年 | 44篇 |
1978年 | 26篇 |
1977年 | 35篇 |
1976年 | 36篇 |
1974年 | 13篇 |
1957年 | 12篇 |
排序方式: 共有10000条查询结果,搜索用时 16 毫秒
31.
32.
Cover Picture: Sequential Anion and Cation Exchange Reactions for Complete Material Transformations of Nanoparticles with Morphological Retention (Angew. Chem. Int. Ed. 30/2015) 下载免费PDF全文
33.
Star copolymers have attracted significant interest due to their different characteristics compared with diblock copolymers, including higher critical micelle concentration, lower viscosity, unique spatial shape, or morphologies. Development of synthetic skills such as anionic polymerization and controlled radical polymerization have made it possible to make diverse architectures of polymers. Depending on the molecular architecture of the copolymer, numerous morphologies are possible, for instance, Archimedean tiling patterns and cylindrical microdomains at symmetric volume fraction for miktoarm star copolymers as well as asymmetric lamellar microdomains for star‐shaped copolymers, which have not been reported for linear block copolymers. In this review, we focus on morphologies and microphase separations of miktoarm (AmBn and ABC miktoarm) star copolymers and star‐shaped [(A‐b‐B)n] copolymers with nonlinear architecture. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 1–21 相似文献
34.
35.
Erdogan Tarcan 《Journal of Macromolecular Science: Physics》2015,54(8):897-906
The dielectric and morphological properties of polythiophene (PT) filled with various mass fractions of chrom(III) acetylacetonate (Cr(acac)3), synthesized via chemical oxidative polymerization, are described. Significant shifts of the absorption peak of the C-S bond in the Fourier transform infrared (FT-IR) spectra indicated that the metal cations mostly interacted with sulfur atoms. Thermal analyses performed by differential scanning calorimetry (DSC) indicated that the cold crystallization temperature (Tcc) of PT decreased with increasing doping level. Microstructural differences were observed between PT and its composites in scanning electron microscopy (SEM) images. Dielectric measurements showed that the conductivity of the PT significantly increased with increasing doping level, from ?10?7 S/m to ?10?4 S/m at 10 kHz and 300 K. 相似文献
36.
Universal power law behavior of the AC conductivity versus frequency of agglomerate morphologies in conductive carbon nanotube‐reinforced epoxy networks 下载免费PDF全文
Brian M. Greenhoe Mohammad K. Hassan Jeffrey S. Wiggins Kenneth A. Mauritz 《Journal of Polymer Science.Polymer Physics》2016,54(19):1918-1923
The Jonscher universal power law for ac conductivity versus frequency (f = ω/2π) in the dispersion region was tested for a multiwall carbon nanotube/epoxy nanocomposite. The effect of changes in agglomerate morphology on the fitting parameters A and n in the equation σac = Aωn was investigated. Changing nanotube agglomerate morphology was tracked by optical microscopy through curing. Evolving morphology was compared alongside ac conductivity obtained via a broadband dielectric spectrometer to elucidate possible physical meaning of the universal power law in the context of this system. The ?logA/n was unaffected by changes in agglomerate morphology affected during cure, yet connected with each other in their dependence on temperature. For this system, the relationship between the fitting parameters in the universal dynamic response equation remains empirical at this stage with regard to biphasic “texture” or morphology within such a network. Electrical conductivity σ versus frequency ω for a composite consisting of agglomerated multiwalled carbon nanotubes dispersed throughout a cured epoxy matrix was discovered to follow the empirical universal dynamic response equation of Jonscher. The frequency behavior of the exponent n is discussed in terms of underlying morphology throughout which charge carriers migrate. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 1918–1923 相似文献
37.
S. Raj Mohan M. P. Joshi C. Shalu C. Ghosh C. Mukharjee L. M. Kukreja 《Journal of Polymer Science.Polymer Physics》2015,53(20):1431-1439
Charge transport properties in thin films of Poly(2‐methoxy‐5‐(3′,7′‐dimethyloctyloxy)‐1,4‐phenylenevinylene) (MDMO PPV) cast using either chloroform (CF), toluene (TOL), or chlorobenzene (CB) as solvent were investigated. Hole mobility (μ) in these thin films measured using time‐of‐flight transient photoconductivity showed an increasing trend with respect to the solvent used in the same order, that is, μCF (2.4 × 10?7 cm2/Vs) < μTOL (6.9 × 10?7 cm2/Vs) < μCB (2.3 × 10?6 cm2/Vs). Observed variations in mobilities were attributed to different morphologies of MDMO PPV chains in thin films cast using the aforesaid solvents. Nature of the interchain interactions and aggregate formation were obtained using photoluminescence (PL), Raman spectroscopy, and AFM studies. Ratio of PL peak intensities of 0–0 and 0–1 transitions, which is a direct measure of interchain interaction, was the highest in CB and lowest in CF. Variation in the relative intensities of out‐of‐plane wagging of vinylene group (~963 cm?1 mode) in Raman spectra suggested different extent of coiling of polymer chains in these thin films. From these observations, it was elicited that aggregate size and interchain interactions are highest in CB and least in CF. AFM‐based topographic images of thin films further supported these variations in the size of aggregates. Variation in the aggregate sizes and interchain interactions explained the corresponding variation in the mobility. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 1431–1439 相似文献
38.
Yuan Xiong Long Ye Chao Zhang 《Journal of polymer science. Part A, Polymer chemistry》2022,60(6):945-960
All-polymer solar cells (all-PSCs) exhibit great potentials in commercial applications. All-PSCs have observed steady performance gains with power conversion efficiency now reaching over 17% in the open literature. However, the current processing of all-PSCs relies predominantly on toxic, chlorinated solvents in moisture-free environments, representing a significant barrier for their commercialization due to the added costs to handle and dispose of such solvents. There is thus an urgent need for safe, environmentally benign, and sustainable ink-based processing methods to produce all-PSC devices reliably and reproducibly in ambient air. In this perspective, fundamental insights on the interplay between all-polymer blend morphologies and eco-friendly solvents are provided. Also, we discuss the recent successes of the green processing methods to manipulate the photoactive morphologies for high-efficiency all-PSCs. In the end, we provide an outlook on future challenges and opportunities of eco-friendly solvents processed all-PSCs for large-scale manufacturing. 相似文献
39.
《Mathematical Methods in the Applied Sciences》2018,41(8):2939-2960
In this paper, we consider a rotating Euler‐Bernoulli beam. The beam is made of a viscoelastic material, and it is subject to undesirable vibrations. Under a suitable control torque applied at the motor, we prove the arbitrary stabilization of the system for a large class of relaxation functions by using the multiplier method and some ideas introduced by Tatar (J. Math. Phys. 52:013502, 2011). 相似文献
40.
Haobing Wang Xia Wu Yang Yang Masayoshi Nishiura Zhaomin Hou 《Angewandte Chemie (International ed. in English)》2020,59(18):7173-7177
The precise control of monomer sequence and stereochemistry in copolymerization is of much interest and importance for the synthesis of functional polymers, but studies toward this goal have met with only limited success to date. Now, the co‐syndiospecific alternating copolymerization of methoxyphenyl‐ and N,N‐dimethylaminophenyl‐functionalized propylenes with styrene by half‐sandwich rare‐earth catalysts is reported. This reaction efficiently afforded the corresponding functionalized propylene‐alt‐styrene copolymers with a perfect alternating sequence and excellent co‐syndiotacticity (rrrr >99 %), thus constituting the first example of co‐stereospecific alternating copolymerization of polar and non‐polar olefins. 相似文献